By Michael P. Doyle
Presents the main cutting edge ends up in carbene chemistry, atmosphere the root for brand new discoveries and applications
The discovery of solid carbenes has reinvigorated carbene chemistry examine, with investigators trying to enhance carbenes into new priceless catalysts and ligands. offering the main leading edge and promising components of carbene learn during the last decade, this booklet explores newly chanced on structural, catalytic, and organometallic points of carbene chemistry, with an emphasis on new and rising man made applications.
Contemporary Carbene Chemistry gains contributions from a global workforce of pioneering carbene chemistry researchers. jointly, those authors have highlighted the main attention-grabbing and promising parts of research within the box. The booklet is split into parts:
- Part 1, homes and Reactions of Carbenes, explores new findings on carbene balance, acid-base habit, and catalysis. Carbenic constitution and reactivity are tested in chapters devoted to strong carbenes, carbodicarbenes, carbenes as site visitors in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited nation precursors. Theoretical matters are addressed in chapters on computational equipment and dynamics utilized to carbene reactions.
- Part 2, steel Carbenes, is devoted to the factitious dimensions of carbenes, fairly the reactions and catalytic homes of steel carbenes. The authors talk about lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold.
All the chapters finish with a precis of the present scenario, new demanding situations at the horizon, and promising new study instructions. a listing of key reports and proposals for additional examining additionally accompanies each chapter.
Each quantity of the Wiley sequence on Reactive Intermediates in Chemistry and Biology makes a speciality of a selected reactive intermediate, supplying a extensive variety of views from prime specialists that units the degree for brand new functions and additional discoveries.
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Additional resources for Contemporary Carbene Chemistry
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